论文全文 - 第28届CIMAC会议 未指定分类
该论文已在赫尔辛基举行的第28届CIMAC大会上发表,论文的版权归CIMAC所有。Gaseous fuels used for gas engines are composed primarily of methane (CH4), but also contain small hydrocarbons, ethane (C2H6), propane (C3H8) and butane (C4H10), and inert gases, carbon dioxide (CO2) and nitrogen (N2). In recent years, the productions of unconventional fuel gases, such as shale gas, and the increasing use of biogas and hydrogen (H2), have led to diversification in the constituents of gaseous fuels. Demand for higher thermal efficiency and greater power has led to high-pressure charging of gas engines, which results in knocking during operation under high loads. Knocking in a spark-ignition engine is occurred when the unburned mixture of end-gas region is ignited prior to flame propagation. The most important determinants of end-gas auto-ignition are the chemical reactivity and physical state of end-gas mixture. As for gaseous fuels containing small hydrocarbons and H2, ignitability, burning velocity and specific heat ratio are significantly different among those components. Accordingly, knock rating using two-component primary reference fuels, such as methane number, can be applied to a limited range. This study investigated the knocking characteristics of H2, C2H6, C3H8, n-C4H10, and iso-C4H10, and also investigated promoting/inhibiting effects of these minor components including CO2 on the incidence of knock with methane-based multi-component fuels. Firstly, engine tests were conducted using neat fuels. Among H2, C2H6, C3H8, n-C4H10, and i-C4H10, H2 possessed the highest knocking tendency. The knock-limited spark advance (KLSA) with H2 was 5 deg. ATDC, while that with n-butane was -23 deg. ATDC. The causes of high knock tendency of H2 were analyzed using zero-dimensional detail chemical kinetic computations, CHEMKIN-PRO. Computed ignition delay time was longest for CH4, followed by H2, C2H6, C3H8, i-C4H10, and n-C4H10. Thus, H2, which is a pro-knock reference fuel of methane number, was less ignitable than the other minor components. The test results were also simulated by setting measured pressure data to constrain pressure model of CHEMKIN-PRO. It was revealed that auto-ignition of H2 was due to the high temperature profile of unburned gas during compression and combustion phase. The higher unburned gas temperature with H2 during the compression stroke is due to the high specific heat ratio of H2 in the mixture. In addition to this effect, the unburned gas temperature with H2 is easy to increase during the combustion phase because of the high burning velocity of H2 which promote compression by flame front. Engine tests were also conducted using CH4-based dual-component fuels having H2, C2H6, C3H8, n-C4H10, or i-C4H10 as their secondary component, and ternary fuels of CH4/H2/CO2. When the proportion of secondary component was small, a CH4/H2 blend showed the lowest knocking tendency. However, as the proportion of secondary component increased, CH4/H2 showed a higher knocking tendency compared to CH4/C2H6. This is due to the high specific heat ratio and burning velocity of H2. Furthermore, addition of CO2 to CH4/H2 significantly increased knock resistance of CH4/H2. This is because CO2 mitigates the high specific heat ratio and burning velocity of H2. The impacts of minor components on knock can be more characteristic of gaseous fuels containing small hydrocarbons than of large hydrocarbons such as gasoline, in which the change in specific heat ratio and burning velocity for different fuel constituents is smaller. The authors believe that taking both of the chemical and physical properties of fuels into account for knock prediction could help to utilize diversified gaseous fuels in the future.
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